Product Identification
【Product Name】1-Bromo-2-iodobenzene
【Synonyms】2-Bromoiodobenzene；邻溴碘苯
【CAS】583-55-1
【Formula】C6H4BrI
【Molecular Weight】282.89999999999998
【EINECS】209-508-9
【Beilstein/Gmelin】1855309
【Beilstein Reference】4-05-00-00698

Physical and Chemical Properties
【Appearance】Clear yellow liquid.
【Solubility in water】Insoluble
【Boiling Point】250℃
【Vapor Pressure】0.04 (25℃)
【Density】2.2571 g/cm3 (25℃)
【Partition Coefficient】3.94
【Heat Of Vaporization】46.7 kJ/mol
【Vapor Density】9.76
【Refractive Index】1.6618 (25℃)

First Aid Measures
【Ingestion】Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage
【Storage】Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from light.
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Store protected from light. Wash clothing before reuse.

Hazards Identification
【Ingestion】May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
【Inhalation】Causes respiratory tract irritation.
【Skin】Causes skin irritation.
【Eyes】Causes eye irritation.
【EC Risk Phrase】R 36/38
【EC Safety Phrase】S 26 36

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Fire Fighting Measures
【Flash Point】105℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.

Stability and Reactivity
【Stability】Stable at room temperature in closed containers under normal storage and handling conditions.
【Incompatibilities】Strong oxidizing agents.
【Decomposition】Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide, hydrogen iodide.